Inorganic Chemistry by Chrispin Kowenje - HTML preview

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2. conduct electricity and heat

3. malleable so they can be hammered into different shapes

4. ductile, so they can be drawn into thin wire

5. high in density. Of all the metals, lead is the highest in density

6. metals have high melting points and most are solids at room temperature

7. mercury is the only metal that is a liquid at room temperature

8. cesium and gallium have low melting points; (melting points are less than

30oC)

9. metals do not combine chemically with each other, but react with nonmetals

to form compounds

10. of all the metals, Group 1 (i.e. alkali metals) are the most reactive

11. metals near the center of the periodic table are less reactive

12. less reactive metals are more likely to be found in nature as uncombined

elements (i.e. copper, silver, gold)

13. reactive metals such as the alkali metals are never found as uncombined ele-

ments (i.e. lithium, sodium)

Many of the properties of metals, including large atomic radius, low ionization energy,

and low electronegativity, are due to the fact that the electrons in the valence shell of

a metal atoms can be removed easily. One characteristic of metals is their ability to

be deformed without breaking. Malleability is the ability of a metal to be hammered

into shapes. Ductility is the ability of a metal to be drawn into wire. Because the

valence electrons can move freely, metals are good heat conductors and electrical

conductors.

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Chemical Properties

Chemically, the metals differ from the nonmetals in that they form positive ions and

basic oxides and hydroxides. Upon exposure to moist air, a great many undergo cor-

rosion, i.e., enter into a chemical reaction; e.g., iron rusts when exposed to moist air,

the oxygen of the atmosphere uniting with the metal to form the oxide of the metal.

Aluminum and zinc do not appear to be affected, but in fact a thin coating of the

oxide is formed almost at once, stopping further action and appearing unnoticeable

because of its close resemblance to the metal. Tin, lead, and copper react slowly un-

der ordinary conditions. Silver is affected by compounds such as sulfur dioxide and

becomes tarnished when exposed to air containing them. The metals are combined

with nonmetals in their salts, as in carbides, carbonates, chlorides, nitrates, phosphates,

silicates, sulfides, and sulfates.

The Electromotive Series

( Kindly look up the series in any inorganic text and study it)

On the basis of their ability to be oxidized, i.e., lose electrons, metals can be arran-

ged in a list called the electromotive series, or replacement series. Metals toward

the beginning of the series, like cesium and lithium, are more readily oxidized than

those toward the end, like silver and gold. In general, a metal will replace any other

metal, or hydrogen, in a compound that it precedes in the series, and under ordinary

circumstances it will be replaced by any metal, or hydrogen, that it follows.

Non-Metals

The Properties of the nonmetals

1. nonmetals have low densities.

2. nonmetals are not ductile or malleable and brittle.

3. nonmetals are not lustrous and are dull.

4. nonmetals are poor conductors of heat and electricity except carbon in the

form of graphite.

5. nonmetals can be found in nature in the uncombined elemental form

6. fluorine is the most reactive of all the nonmetals.

7. nonmetals can combine with other nonmetals to form compounds such as:

carbon dioxide (CO ), carbon monoxide (CO), methane (CH ), and ammonia

2

4

(NH ).

3

Metalloids / semimetals

The Properties of the Semimetals

1. semimetals have both metallic and nonmetallic properties

2. semimetals are semiconductors, in other words, they are not as conducting as

metals and are not insulators like the nonmetals (i.e. silicon and gallium arsenide

(GaAs) are used widely in the semiconductor industry)

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Block elements

Alkali metals

The alkali metals are lithium, sodium, potassium, rubidium, cesium, and francium

(Li, Na, K, Rb, Cs, and Fr respectively). Hydrogen is often considered to be an alkali

metal (especially at low temperatures or high pressures), although some scientists

think of it as a nonmetal. The alkali metals are the elements located in Group IA (first

column) of the periodic table.

In many of its properties, lithium, exhibits the same characteristics as do the more

common alkali metals sodium and potassium; thus, the metal is highly reactive and

forms strong hydroxide solutions. In many respects lithium also shows similarities

to the elements of the alkaline-earth group, especially magnesium, which has similar

atomic and ionic radii.

Summary of Common Properties

1. Lower densities than other metals,

2. One loosely bound valence electrons

3. Largest atomic radii in their periods,

4. Low ionization energies,

5. Low electronegativities,